4-Bromo-1H-benzo[d]imidazol-2-amine

Name: 4-Bromo-1H-benzo[d]imidazol-2-amine
Brand: ChemScene
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CAS No. 1266114-75-3
Cat. No. CS-W021050
Molecule weight211.06
Purity≥98%
MDL No.MFCD09907621

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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4-Bromo-1H-benzo[d]imidazol-2-amine|CS-W021050

Structure of 1266114-75-3

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General Information

CAS No. 1266114-75-3
Cat. No. CS-W021050
Purity ≥98%
MDL No. MFCD09907621
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₇BrN₂
Molecular Weight 211.06
Synonym(s) 4-Bromo-2-methyl-1H-benzoimidazole
SMILES NC1=NC2=C(N1)C=CC=C2Br

Description

4-Bromo-1H-benzo[d]imidazol-2-amine features a bromine substituent at the C4 position of a benzoimidazole core, imparting enhanced reactivity for cross-coupling transformations. The nitrogen-rich heterocyclic scaffold offers strong coordination potential and stability under standard reaction conditions, enabling efficient integration into bioactive molecules and functional materials.

Application

4-Bromo-1H-benzo[d]imidazol-2-amine serves as a versatile building block in medicinal chemistry, enabling efficient access to biologically relevant heterocyclic scaffolds. The bromine atom facilitates palladium-catalyzed cross-coupling reactions, while the amino group supports derivatization via acylation, alkylation, or electrophilic substitution. Its bench-stable nature and compatibility with diverse reaction conditions make it well-suited for iterative synthesis campaigns in API development.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H319
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 54.7
LogP 1.9076
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Benzimidazole compounds

Key Words

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4-Bromo-1H-benzo[d]imidazol-2-amine

CAS No. 1266114-75-3

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