4'-Chloro-2,2':6',2''-terpyridine

Name: 4'-Chloro-2,2':6',2''-terpyridine
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CAS No. 128143-89-5
Cat. No. CS-W004586
Purity≥96%
MDL No.MFCD00191930

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Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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4'-Chloro-2,2':6',2''-terpyridine|CS-W004586

Structure of 128143-89-5

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Description

4-Chloro-2,2:6,2-terpyridine (4-Cltpy, Cltpy, Cl-terpy) is a tridentate ligand that contains a terpyridine (tpy) site with a Cl site at the 4 -position. It coordinates with various metal ions through these two sites to form different coordination polymers. Crystal structure study shows terpyridine unit of Cltpy adopts a trans, trans conformation. Molecules assemble themselves into stacked columns along the b axis, with an interplanar distance of 3.51. It undergoes Williamson type ether reactions with ,-bishydroxy-functionalized poly(propylene oxide). It undergoes Williamson type reaction with -hydroxy--carboxy-functionalized poly(ethylen-oxide) to afford monoterpyridine terminated telechelics.4-Chloro-2,2:6,2-terpyridine may be used in the preparation of the following:mono- and bis-terpyridinesbis-hydroxy-functionalized terpyridine cadmium(II) complex and a fullerene derivative4-functionalized 2,2:6,2-terpyridines, building blocks for novel supramolecular structures, such as double helicates, dendrimers, micelles and metallo-supramolecular polymers

General Information

CAS No. 128143-89-5
Cat. No. CS-W004586
Purity ≥96%
MDL No. MFCD00191930
Storage RT, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₅H₁₀ClN₃
Molecular Weight 267.72
Synonym(s) 4'-Chloro-α,α',α''-tripyridyl
SMILES ClC=1C=C(N=C(C1)C=2N=CC=CC2)C3=NC=CC=C3

Computational Chemistry Data

TPSA 38.67
LogP 3.859
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 2

Safety Information

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GHS Pictogram :	GHS No : GHS05,GHS06
Signal Word : Danger	UN#: 2811
Class : 6.1	Packing Group : Ⅲ
Hazard Statements : H301-H315-H318-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P362-P403+P233-P405-P501

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Other Classifications

Catalysts and Ligands Ligands Pyridine Ligands Terpyridine Ligands

Material Science Material Building Blocks Ligands for Functional Metal Complexes Bipyridine Ligands, Terpyridine Ligands

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Catalysis Nitrogen-Donor Ligands Pyridine Ligands

Catalysis Nitrogen-Donor Ligands Bipyridine Ligands, Terpyridine Ligands

Key Words

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4'-Chloro-2,2':6',2''-terpyridine

CAS No. 128143-89-5

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