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CS-W001157 4
Total: USD 88.00

Cobalt(1+), bis[[2,3-butanedione 2,3-di(oximato-κN)](1-)]bis(pyridine)-, (OC-6-12)-, hexafluorophosphate(1-) 1:1

  • CAS No. 139526-58-2

  • Cat. No. CS-0642645
  • Molecule weight593.33
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

Cobalt(1+), bis[[2,3-butanedione 2,3-di(oximato-κN)](1-)]bis(pyridine)-, (OC-6-12)-, hexafluorophosphate(1-) 1:1|CS-0642645

Structure of 139526-58-2

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General Information

  • CAS No. 139526-58-2
  • Cat. No. CS-0642645
  • Purity ≥98%
  • MDL No. None
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₈H₂₅CoF₆N₆O₄P+
  • Molecular Weight 593.33
  • Synonym(s) None
  • SMILES F[P-](F)(F)(F)(F)F.[O-][N]([Co+3]([N](O)=C1C)([N](O)=C2C)([N]3=CC=CC=C3)([N]4=CC=CC=C4)[N](O)=C1C)=C2C

Description

Cobalt(1+), bis[[2,3-butanedione 2,3-di(oximato-κN)](1-)]bis(pyridine)-, (OC-6-12)-, hexafluorophosphate(1-) (1:1) is a stable, air-tolerant cobalt complex featuring two oxime ligands and two pyridine donors. This coordination structure delivers enhanced solubility in organic solvents and facilitates redox-active transformations under mild conditions.

Application

This cobalt(1+) complex serves as a robust, bench-stable catalyst for selective C–H functionalization and cross-coupling reactions. Its bis(oxime) ligand framework enables precise control over reactivity, while the pyridine coordination sphere enhances solubility and stability under standard synthetic conditions. The hexafluorophosphate counterion facilitates easy handling and compatibility with common purification methods. Functions effectively in transition-metal-catalyzed transformations involving heterocyclic substrates and carbonyl derivatives.

Safety Information

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GHS Pictogram :
GHS No : GHS02,GHS05,GHS07,GHS08
Signal Word : Danger
UN#: 1325
Class : 4.1
Packing Group : Ⅲ
Hazard Statements : H228-H302+H312+H332-H315-H317-H319-H334-H351
Precautionary Statements : P210-P240-P241-P261-P264-P270-P271-P272-P280-P284-P302+P352-P304+P340-P330-P362+P364-P370+P378-P405-P501

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Computational Chemistry Data

  • TPSA   N/A
  • LogP   N/A
  • H_Acceptors   10
  • H_Donors   3
  • Rotatable_Bonds   N/A

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