5,10,15,20-Tetraphenyl-21H,23H-porphine copper(II)

Name: 5,10,15,20-Tetraphenyl-21H,23H-porphine copper(II)
Brand: ChemScene
Availability: InStock
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CAS No. 14172-91-9
Cat. No. CS-0086028
Molecule weight676.28
Purity≥95%
MDL No.MFCD00148862

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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5,10,15,20-Tetraphenyl-21H,23H-porphine copper(II)|CS-0086028

Structure of 14172-91-9

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General Information

CAS No. 14172-91-9
Cat. No. CS-0086028
Purity ≥95%
MDL No. MFCD00148862
Storage RT, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄₄H₂₈CuN₄
Molecular Weight 676.28
Synonym(s) Copper(II) TPP
SMILES C=1C=CC(=CC1)C=2C=3C=CC4=C(C=5C=CC=CC5)C6=CC=C7C(C=8C=CC=CC8)=C9C=CC=%10C(C=%11C=CC=CC%11)=C%12C=CC2[N-]%12[Cu+2]([N]34)([N]%109)[N-]67

Description

Copper(II) complex of 5,10,15,20-tetraphenyl-21H,23H-porphine features a central Cu²⁺ ion coordinated within a planar, electron-deficient porphyrin core. The four phenyl rings enhance solubility and steric protection, while the metal center enables redox activity and catalytic function in oxidation reactions. This robust complex serves as a stable platform for applications in photodynamic therapy, molecular catalysis, and electrochemical sensing.

Application

Copper(II) 5,10,15,20-tetraphenyl-21H,23H-porphine serves as a robust and bench-stable porphyrin-based catalyst for oxidation reactions and oxygenation processes. Its well-defined coordination geometry facilitates efficient electron transfer and substrate activation, enabling reliable performance in catalytic cycles. The tetraphenyl substitution enhances solubility and stability, while the copper(II) center provides accessible redox activity for applications in synthetic organic chemistry and materials science.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors 2
H_Donors 0
Rotatable_Bonds N/A

Other Classifications

Catalysts and Ligands Catalysts Transition Metal Catalysts Cu Catalysts

Material Science Magnetic Materials Magnetic Metal Complexes Phthalocyanine Complexes, Porphyrin Complexes

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Photonic Materials, Optical Materials Phthalocyanine Dyes, Porphyrin Dyes

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Catalysis Asymmetric Synthesis Chiral Catalysts, Chiral Ligands, Chiral Reagents Chiral Catalysts (Other)

Catalysis C-H Activation Copper Compounds

Catalysis Compounds by Element Classes Metal Compounds Transition Metal Compounds

Catalysis Cross-coupling Reaction using Transition Metal Catalysts Copper Catalysts

Catalysis Non-Precious Metal Catalysis

Catalysis Transition Elements Copper

Key Words

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5,10,15,20-Tetraphenyl-21H,23H-porphine copper(II)

CAS No. 14172-91-9

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