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Structure of 14564-35-3
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Bis(triphenylphosphine)ruthenium(II) dicarbonyl chloride features a ruthenium(II) center coordinated by two triphenylphosphine ligands and two carbonyl groups, with a chloride counterion. This air-stable complex serves as a versatile precursor in organometallic synthesis, enabling efficient catalytic transformations under mild conditions. The phosphine ligands enhance solubility and stabilize the metal center during reductive processes.
Bis(triphenylphosphine)ruthenium(II) dicarbonyl chloride serves as a well-established precatalyst in transition-metal-catalyzed transformations, particularly in carbonylative coupling reactions and C–H functionalization processes. Its bench-stable nature, tolerance to air and moisture under controlled conditions, and predictable reactivity enable reliable formation of active ruthenium species. The ligand set facilitates CO insertion and oxidative addition steps, making it a practical choice for synthesizing ketones, amides, and heterocyclic scaffolds in medicinal chemistry and process development workflows.
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GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Lot numbers can be found on the outside label of a product: