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CS-W001157 4
Total: USD 88.00

Dichloro(benzene)ruthenium(II) dimer

  • CAS No. 37366-09-9

  • Cat. No. CS-0081037
  • Purity≥97%
  • MDL No.MFCD00064686

*For research and further manufacturing use only, not for direct human use.

Dichloro(benzene)ruthenium(II) dimer|CS-0081037

Structure of 37366-09-9

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General Information

  • CAS No. 37366-09-9
  • Cat. No. CS-0081037
  • Purity ≥97%
  • MDL No. MFCD00064686
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₂H₁₂Cl₄Ru₂
  • Molecular Weight 500.18
  • Synonym(s) Benzeneruthenium(II) chloride dimer
  • SMILES Cl[Ru](Cl1)Cl[Ru]1Cl.c2ccccc2.c3ccccc3

Description

Hydrosilylation CatalystsCatalyst for SNAr reactions of fluoroarenes and cyclic amines (eq. 1)Precatalyst for the hydrogenation of -keto esters (eq. 2)Precursor for the preparation of other ruthenium catalysts (eq. 3)

Synthesis

  • Route1
    • In-stock
      Ruthenium(III) chloride|CS-W020395
      10049-08-8
    • null|null
      1165952-91-9
    • ~78%
    • In-stock
      Dichloro(benzene)ruthenium(II) dimer|CS-0081037
      37366-09-9

    References

    • Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 36, p. 1922 - 1926 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 2071 - 2076
  • Route2
    • Ruthenium(III) chloride monohydrate|CS-0031493
      20759-14-2
    • null|null
      1165952-92-0
    • ~80%
    • In-stock
      Dichloro(benzene)ruthenium(II) dimer|CS-0081037
      37366-09-9

    References

    • Journal of the Chemical Society. Perkin Transactions 1, , # 3 p. 416 - 427
  • Route3
    • null|null
      54913-13-2
    • ~%
    • In-stock
      Dichloro(benzene)ruthenium(II) dimer|CS-0081037
      37366-09-9

    References

    • Journal of Organometallic Chemistry, , vol. 354, p. 117 - 122

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362

Quality Control

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Computational Chemistry Data

  • TPSA   N/A
  • LogP   N/A
  • H_Acceptors   N/A
  • H_Donors   N/A
  • Rotatable_Bonds   N/A

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