(Tetrahydropyran-3-yl)methanol

Name: (Tetrahydropyran-3-yl)methanol
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CAS No. 14774-36-8
Cat. No. CS-D0478
Purity≥97%
MDL No.MFCD08235011

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 14774-36-8

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Description

This bench-stable, moisture-tolerant protecting group features a tetrahydropyran ring that selectively masks hydroxyl functionalities under standard conditions. The pendant methanol moiety enables facile deprotection via acid-catalyzed cleavage, offering high chemoselectivity in complex molecule synthesis.

Application

(Tetrahydropyran-3-yl)methanol serves as a robust, bench-stable protecting group for alcohols and carboxylic acids, enabling selective deprotection under mild acidic conditions. Its orthogonality to other common protecting groups facilitates sequential functionalization in complex molecule synthesis. The tetrahydropyranyl moiety enhances solubility and stability during multi-step transformations, while the primary alcohol functionality allows further derivatization. This reagent is particularly valuable in carbohydrate chemistry and medicinal chemistry workflows requiring controlled protection strategies.

General Information

CAS No. 14774-36-8
Cat. No. CS-D0478
Purity ≥97%
MDL No. MFCD08235011
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₁₂O₂
Molecular Weight 116.16
Synonym(s) tetrahydro-2H-pyran-3-methanol
SMILES OCC1COCCC1

Computational Chemistry Data

TPSA 29.46
LogP 0.4053
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Skeleton Aliphatic heterocycle compounds Tetrahydropyran compounds

Key Words

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(Tetrahydropyran-3-yl)methanol

CAS No. 14774-36-8

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