(Tetrahydro-2H-pyran-4-yl)methanol

Name: (Tetrahydro-2H-pyran-4-yl)methanol
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CAS No. 14774-37-9
Cat. No. CS-D1227
Purity≥98%
MDL No.MFCD00457804

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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(Tetrahydro-2H-pyran-4-yl)methanol|CS-D1227

Structure of 14774-37-9

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Description

Tetrahydro-2H-pyran-4-yl)methanol serves as a robust protecting group for alcohols, offering high stability under basic and mildly acidic conditions. This hydroxymethyl derivative integrates seamlessly into complex synthetic sequences, where its orthogonality to other functional groups enables selective deprotection. The tetrahydropyranyl moiety provides excellent solubility in common organic solvents and facilitates purification via standard chromatographic methods.

Application

(Tetrahydro-2H-pyran-4-yl)methanol serves as a versatile protecting group for alcohols and a key building block in carbohydrate chemistry. Its tetrahydropyran ring provides excellent stability under a range of reaction conditions, while the pendant hydroxymethyl group enables selective transformations. The molecule facilitates orthogonal protection strategies and functions effectively in multi-step syntheses requiring robust functional group tolerance and ease of removal under mild acidic conditions.

General Information

CAS No. 14774-37-9
Cat. No. CS-D1227
Purity ≥98%
MDL No. MFCD00457804
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₁₂O₂
Molecular Weight 116.16
Synonym(s) None
SMILES OCC1CCOCC1

Computational Chemistry Data

TPSA 29.46
LogP 0.4053
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Bioactive Molecules Dye and Bio-assay Reagents

Building Blocks Functional Group Alcohol

Building Blocks Skeleton Aliphatic heterocycle compounds Tetrahydropyran compounds

Key Words

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(Tetrahydro-2H-pyran-4-yl)methanol

CAS No. 14774-37-9

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