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Structure of 162067-50-7
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Cesium pivalate is an organic base widely used in palladium-catalyzed cross-coupling and carbonylation reactions due to its solubility in organic solvents.Cesium pivalate can be used as a base to synthesize:Fluoren-9-one derivatives by cyclocarbonylation of o-halobiaryls in the presence of palladium catalyst.Fused heterocycles (dihydrobenzofurans and indolines) from o-bromo phenol and aniline precursors via Pd-catalyzed intramolecular coupling of two C(sp3)-H bonds.Amides and esters derivatives containing a quaternary -carbon atom by Pd-catalyzed C-H activation and amino/alkoxycarbonylation reaction.It can also be used as a base in the palladium-catalyzed Mizoroki-Heck reaction.
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GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H315-H319-H335
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Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P362+P364-P403+P233-P405-P501
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Lot numbers can be found on the outside label of a product: