2-Chloro-4-methoxyphenol

Name: 2-Chloro-4-methoxyphenol
Brand: ChemScene
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CAS No. 18113-03-6
Cat. No. CS-W008217
Purity≥98%
MDL No.MFCD00070773

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 18113-03-6

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Description

2-Chloro-4-methoxyphenol offers a strategic combination of electron-donating and halogenated functionality, enabling efficient coupling in cross-coupling and Ullmann-type reactions. The para-methoxy group enhances solubility and stabilizes reaction intermediates, while the ortho-chlorine serves as a direct handle for palladium-catalyzed transformations. This phenolic scaffold integrates readily into bioactive molecule design, particularly in agrochemical and pharmaceutical synthesis pathways.

Application

2-Chloro-4-methoxyphenol serves as a versatile intermediate in the synthesis of pharmaceuticals and agrochemicals, enabling efficient functionalization via palladium-catalyzed cross-coupling reactions. Its ortho-chloro and para-methoxy substituents provide orthogonal reactivity for selective transformations, while the phenolic hydroxyl group allows for derivatization or protection. The compound exhibits good bench stability and facilitates straightforward purification, making it well-suited for scalable synthetic processes.

General Information

CAS No. 18113-03-6
Cat. No. CS-W008217
Purity ≥98%
MDL No. MFCD00070773
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇ClO₂
Molecular Weight 158.58
Synonym(s) Phenol, 2-chloro-4-methoxy-; 2-Chloro-4-methoxyphenol
SMILES C1=C(C(=CC=C1OC)O)Cl

Computational Chemistry Data

TPSA 29.46
LogP 2.0542
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Chloro-4-methoxyphenol

CAS No. 18113-03-6

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