3-Chloro-5-hydroxybenzaldehyde

Name: 3-Chloro-5-hydroxybenzaldehyde
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CAS No. 1829-33-0
Cat. No. CS-W006258
Purity≥98%
MDL No.MFCD08234659

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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3-Chloro-5-hydroxybenzaldehyde|CS-W006258

Structure of 1829-33-0

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General Information

CAS No. 1829-33-0
Cat. No. CS-W006258
Purity ≥98%
MDL No. MFCD08234659
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₅ClO₂
Molecular Weight 156.57
Synonym(s) None
SMILES O=CC1=CC(O)=CC(Cl)=C1

Description

3-Chloro-5-hydroxybenzaldehyde features a hydroxyl group flanked by electron-withdrawing chlorine and aldehyde functionalities, enabling selective coupling reactions. This ortho-directed reactivity profile supports efficient synthesis of functionalized aromatics under mild conditions.

Application

3-Chloro-5-hydroxybenzaldehyde serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling efficient access to substituted benzimidazoles, quinoline derivatives, and other heterocyclic scaffolds. The ortho-chloro and para-hydroxy groups provide complementary reactivity for palladium-catalyzed coupling and directed metalation, while the aldehyde functionality supports reductive amination, imine formation, and Ullmann-type cyclizations. Bench-stable and amenable to standard purification methods, it facilitates reliable multi-step syntheses.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 37.3
LogP 1.8581
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Functional Group Aldehyde

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Chloro-5-hydroxybenzaldehyde

CAS No. 1829-33-0

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