Phenyl formate

Name: Phenyl formate
Brand: ChemScene
Availability: InStock
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CAS No. 1864-94-4
Cat. No. CS-0119930
Molecule weightNone
Purity≥97%
MDL No.MFCD00014126

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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Structure of 1864-94-4

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General Information

CAS No. 1864-94-4
Cat. No. CS-0119930
Purity ≥97%
MDL No. MFCD00014126
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₆O₂
Molecular Weight None
Synonym(s) Phenoxyformaldehyde
SMILES O=COC1=CC=CC=C1

Description

Dextran is a polymer of anhydroglucose. It is composed of approximately 95% alpha-D-(166) linkages. The remaining (163) linkages account for the branching of dextran. Conflicting data on the branch lengths implies that the average branch length is less than three glucose units. However, other methods indicate branches of greater than 50 glucose units exist. Native dextran has been found to have a molecular weight (MW) in the range of 9 million to 500 million. Lower MW dextrans will exhibit slightly less branching and have a more narrow range of MW distribution. Dextrans with MW greater than 10,000 behave as if they are highly branched. As the MW increases, dextran molecules attain greater symmetry. Dextrans with MW of 2,000 to 10,000, exhibit the properties of an expandable coil. At MW below 2,000, dextran is more rod-like. The MW of dextran is measured by one or more of the following methods: low angle laser light scattering, size exclusion chromatography, copper-complexation and anthrone reagent colorometric reducing-end sugar determination and viscosity.Dextran labeled with fluorescein isothiocyanate for possible use in perfusion studies in animals.

Synthesis

Route1
- 64-18-6
- 108-95-2
- ~72%
- In-stock
  
  1864-94-4
References
- Katafuchi, Yuko; Fujihara, Tetsuaki; Iwai, Tomohiro; Terao, Jun; Tsuji, Yasushi Advanced Synthesis and Catalysis, 2011 , vol. 353, # 2-3 p. 475 - 482
Route2
- 2258-42-6
- 108-95-2
- ~%
- In-stock
  
  1864-94-4
References
- Ueda, Tsuyoshi; Konishi, Hideyuki; Manabe, Kei Tetrahedron Letters, 2012 , vol. 53, # 38 p. 5171 - 5175
Route3
- 100-52-7
- ~91%
- In-stock
  
  1864-94-4
References
- Ochiai, Masahito; Yoshimura, Akira; Miyamoto, Kazunori; Hayashi, Satoko; Nakanishi, Waro Journal of the American Chemical Society, 2010 , vol. 132, # 27 p. 9236 - 9239

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H227-H302-H315-H319-H335-H412
Precautionary Statements : P210-P261-P264-P270-P271-P273-P280-P302+P352-P304+P340-P330-P362+P364-P370+P378-P403-P405-P501

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Computational Chemistry Data

TPSA 26.3
LogP 1.2218
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Aldehyde

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Chemical Synthesis Synthetic Reagents C-C Bond Formation Carbon Monoxide Surrogate Reagents

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Phenyl formate

CAS No. 1864-94-4

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