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CS-W001157 4
Total: USD 88.00

Bis[1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl-κO]methanesulfonamidato-κO]-,cobalt

  • CAS No. 207861-61-8

  • Cat. No. CS-0103965
  • Molecule weight619.23
  • Purity≥98%
  • MDL No.MFCD23380169

*For research and further manufacturing use only, not for direct human use.

Bis[1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl-κO]methanesulfonamidato-κO]-,cobalt|CS-0103965

Structure of 207861-61-8

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General Information

  • CAS No. 207861-61-8
  • Cat. No. CS-0103965
  • Purity ≥98%
  • MDL No. MFCD23380169
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₄CoF₁₂N₂O₈S₄
  • Molecular Weight 619.23
  • Synonym(s) Cobalt bis(trifluoroMethylsulfonyl)iMide
  • SMILES O=S1(C(F)(F)F)=O[Co+2](O=2)(O=S([N-]1)(C(F)(F)F)=O)O=S([N-]S2(C(F)(F)F)=O)(C(F)(F)F)=O

Description

Cobalt(III) bis(trifluoromethanesulfonamidate) features a highly fluorinated coordination sphere, delivering exceptional thermal and oxidative stability. This bench-stable complex integrates into high-temperature catalytic systems, enabling efficient C–H functionalization under mild conditions. The electron-deficient ligands enhance redox activity while resisting moisture degradation.

Application

Bis[1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl-κO]methanesulfonamidato-κO]cobalt serves as a robust, bench-stable cobalt(III) source for catalytic C–H functionalization and cross-coupling reactions. Its trifluoromethylsulfonyl groups enhance oxidative stability and facilitate ligand exchange, enabling efficient transformations under mild conditions. The complex exhibits high functional group tolerance and is well-suited for the synthesis of fluorinated heterocycles and pharmaceutical intermediates.

Safety Information

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GHS Pictogram :
GHS No : GHS05
Signal Word : Danger
UN#: 1759
Class : 8
Packing Group : Ⅱ
Hazard Statements : H314
Precautionary Statements : P261-P272-P280-P302+P352-P363-P405-P501

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Computational Chemistry Data

  • TPSA   N/A
  • LogP   N/A
  • H_Acceptors   8
  • H_Donors   0
  • Rotatable_Bonds   N/A

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