t-Butyl 2-bromo isobutyrate

Name: t-Butyl 2-bromo isobutyrate
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CAS No. 23877-12-5
Cat. No. CS-W001075
Purity≥98%
MDL No.MFCD00051908

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

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Description

tert-Butyl -bromoisobutyrate was used as an initiator in the atom transfer radical polymerisation (ATRP) of 2-(acetoacetoxy)ethyl methacrylate (AEMA).

Application

tert-Butyl 2-bromo-2-methylpropanoate serves as a robust, bench-stable building block for the synthesis of sterically hindered carboxylic acid derivatives. Its tertiary alkyl bromide functionality enables efficient nucleophilic substitution reactions, facilitating the construction of quaternary carbon centers. The tert-butyl ester group provides excellent stability under basic conditions and can be readily cleaved via mild acidic hydrolysis, offering a versatile handle for downstream functionalization in complex molecule assembly.

General Information

CAS No. 23877-12-5
Cat. No. CS-W001075
Purity ≥98%
MDL No. MFCD00051908
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₁₅BrO₂
Molecular Weight 223.11
Synonym(s) tert-butyl-α-bromoisobutyrate
SMILES O=C(C(Br)(C)C)OC(C)(C)C

Computational Chemistry Data

TPSA 26.3
LogP 2.5016
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335-H412
Precautionary Statements : P261-P264-P270-P271-P273-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Fatty chain compounds

Material Science Biomaterials/Biocompatible Materials Research Reagents Polymerization Reagents (Initiators, Catalysts, Ligands) Atom Transfer Radical Polymerization (ATRP) Reagents

Material Science Polymer/Macromolecule Reagents Polymerization Reagents Controlled Radical Polymerization Reagents

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t-Butyl 2-bromo isobutyrate

CAS No. 23877-12-5

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