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CS-W001157 4
Total: USD 88.00

1,8-Diiodooctane

  • CAS No. 24772-63-2

  • Cat. No. CS-0196432
  • Purity≥97%
  • MDL No.MFCD00001106

*For research and further manufacturing use only, not for direct human use.

1,8-Diiodooctane|CS-0196432

Structure of 24772-63-2

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General Information

  • CAS No. 24772-63-2
  • Cat. No. CS-0196432
  • Purity ≥97%
  • MDL No. MFCD00001106
  • Storage 4°C, protect from light
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₈H₁₆I₂
  • Molecular Weight 366.02
  • Synonym(s) None
  • SMILES ICCCCCCCCI

Description

1,8-Diiodooctane has been employed as processing additive:to improve the morphology and the efficiency of bulk heterojunctions solar cells, based on the regioregular poly(3-hexylthiophene) and a soluble fullerene derivativeto improve the power conversion efficiency of polymer solar cells

Application

1,8-Diiodooctane serves as a versatile diiodide building block for constructing cyclic and linear scaffolds via coupling reactions. Its extended aliphatic chain provides favorable solubility and low volatility, enhancing handling and purification. The geminal diiodide functionality enables efficient cross-coupling with palladium catalysts, facilitating the synthesis of conjugated polymers and macrocyclic architectures. This reagent exhibits robust bench stability and functional group tolerance, making it well-suited for iterative synthetic sequences in materials science and medicinal chemistry applications.

Synthesis

  • Route1

    References

    • Leadbeater, Nicholas E.; Torenius, Hanna M.; Tye, Heather Tetrahedron, 2003 , vol. 59, # 13 p. 2253 - 2258
  • Route2

    References

    • Journal of Organic Chemistry, , vol. 47, # 3 p. 564 - 566
  • Route3

    References

    • Journal of Chemical Research, Miniprint, , # 1 p. 101 - 132

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   4.197
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   7

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