(OC-6-22)-Bis(acetato-κO,κO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]ruthenium

Name: (OC-6-22)-Bis(acetato-κO,κO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]ruthenium
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CAS No. 261948-85-0
Cat. No. CS-0035253
Molecule weight841.83
Purity≥98%
MDL No.None

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(OC-6-22)-Bis(acetato-κO,κO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]ruthenium|CS-0035253

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General Information

CAS No. 261948-85-0
Cat. No. CS-0035253
Purity ≥98%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄₈H₃₈O₄P₂Ru
Molecular Weight 841.83
Synonym(s) Ru(OAc)2[(S)-binap]
SMILES CC1=O[Ru]23([P](C4=CC=CC=C4)(C5=CC=CC=C5)C6=[C@]([C@]7=C(C=CC=C8)C8=CC=C7[P]2(C9=CC=CC=C9)C%10=CC=CC=C%10)C%11=C(C=CC=C%11)C=C6)(OC(C)=O3)O1

Description

This ruthenium complex features a chiral binaphthyl backbone with two diphenylphosphine arms and acetate ligands, enabling asymmetric catalysis in cross-coupling reactions. The rigid, electron-rich structure promotes high enantioselectivity and stability under reaction conditions.

Application

This ruthenium complex serves as a highly effective catalyst in asymmetric hydrogenation and C–H functionalization reactions, leveraging the chiral binaphthyl backbone and robust phosphine-acetate ligand framework. Its bench-stable nature and tolerance to diverse functional groups enable reliable performance in multistep synthesis. The structure facilitates enantioselective transformations with high reproducibility, making it a practical choice for constructing chiral scaffolds in pharmaceutical and agrochemical research.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

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(OC-6-22)-Bis(acetato-κO,κO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]ruthenium

CAS No. 261948-85-0

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