(4R,5R)-2-(2-(Diphenylphosphino)phenyl)-4,5-diphenyl-4,5-dihydrooxazole

Name: (4R,5R)-2-(2-(Diphenylphosphino)phenyl)-4,5-diphenyl-4,5-dihydrooxazole
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CAS No. 2680585-79-7
Cat. No. CS-0611038
Purity≥98%
MDL No.None

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(4R,5R)-2-(2-(Diphenylphosphino)phenyl)-4,5-diphenyl-4,5-dihydrooxazole|CS-0611038

Structure of 2680585-79-7

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Description

This oxazole scaffold features a chiral backbone with dual aryl substituents and a diphenylphosphino group positioned ortho to the heterocycle, enabling effective coordination in asymmetric catalysis. The rigid, electron-rich architecture supports stable complexation with transition metals, facilitating enantioselective transformations under standard conditions.

Application

(4R,5R)-2-(2-(Diphenylphosphino)phenyl)-4,5-diphenyl-4,5-dihydrooxazole serves as a versatile chiral ligand scaffold in transition metal catalysis, enabling asymmetric synthesis through well-established palladium- and rhodium-catalyzed transformations. Its rigid, electron-rich diphenylphosphinoaryl moiety facilitates efficient coordination to metal centers, while the dihydrooxazole ring provides stereochemical control and enhanced bench stability. This compound functions effectively in cross-coupling reactions and enantioselective hydrogenation processes, offering predictable reactivity and straightforward purification in industrial R&D workflows.

General Information

CAS No. 2680585-79-7
Cat. No. CS-0611038
Purity ≥98%
MDL No. None
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₃H₂₆NOP
Molecular Weight 483.54
Synonym(s) (4R,5R)-2-(2-(Diphenylphosphanyl)phenyl)-4,5-diphenyl-4,5-dihydrooxazole
SMILES P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=C(C4=N[C@H](C5=CC=CC=C5)[C@@H](C6=CC=CC=C6)O4)C=CC=C3

Computational Chemistry Data

TPSA 21.59
LogP 6.7042
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 6

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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(4R,5R)-2-(2-(Diphenylphosphino)phenyl)-4,5-diphenyl-4,5-dihydrooxazole

CAS No. 2680585-79-7

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