Ethyl 3-bromo-2,2-dimethylpropanoate

Name: Ethyl 3-bromo-2,2-dimethylpropanoate
Brand: ChemScene
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CAS No. 2843-18-7
Cat. No. CS-0140566
Purity≥97%
MDL No.None

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FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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Ethyl 3-bromo-2,2-dimethylpropanoate|CS-0140566

Structure of 2843-18-7

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Description

Ethyl 3-bromo-2,2-dimethylpropanoate is a sterically hindered bromoester featuring a quaternary carbon center, enabling selective alkylation reactions under mild conditions. This bench-stable reagent integrates readily into synthetic sequences requiring constrained electrophilic sites, particularly in the construction of densely functionalized building blocks for medicinal chemistry and natural product synthesis.

Application

Ethyl 3-bromo-2,2-dimethylpropanoate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to sterically hindered alkylated scaffolds. Its α-bromination facilitates nucleophilic substitution reactions with high regioselectivity, while the ester functionality supports subsequent transformations such as hydrolysis or reduction. The tert-butyl-like steric environment enhances stability and simplifies purification, making it well-suited for iterative synthesis and scale-up in medicinal chemistry workflows.

General Information

CAS No. 2843-18-7
Cat. No. CS-0140566
Purity ≥97%
MDL No. None
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₁₃BrO₂
Molecular Weight 209.08
Synonym(s) Brom-pivalinsaeure-aethylester
SMILES O=C(OCC)C(C)(C)CBr

Computational Chemistry Data

TPSA 26.3
LogP 1.9706
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 3

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Fatty chain compounds

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Ethyl 3-bromo-2,2-dimethylpropanoate

CAS No. 2843-18-7

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