3,6-Dioxabicyclo[3.1.0]hexane

Name: 3,6-Dioxabicyclo[3.1.0]hexane
Brand: ChemScene
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CAS No. 285-69-8
Cat. No. CS-W016680
Purity≥95%
MDL No.MFCD00800639

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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3,6-Dioxabicyclo[3.1.0]hexane|CS-W016680

Structure of 285-69-8

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Description

3,6-Dioxabicyclo[3.1.0]hexane serves as a rigid, electron-rich scaffold for molecular diversification. This bicyclic acetal features two oxygen atoms at bridgehead positions, enabling stable integration into complex architectures. The constrained geometry enhances regioselectivity in downstream transformations, while the acetal functionality offers controlled release under acidic conditions. Ideal for medicinal chemistry and materials synthesis, it delivers predictable stereochemical outcomes.

Application

3,6-Dioxabicyclo[3.1.0]hexane serves as a rigid, bicyclic scaffold enabling precise spatial control in synthetic design. Its stable dioxane ring system exhibits excellent bench stability and tolerates a range of functional groups, facilitating efficient incorporation into complex molecular architectures. Functions as a key building block for heterocyclic systems and bioactive molecule synthesis, particularly in medicinal chemistry applications requiring conformational constraint.

General Information

CAS No. 285-69-8
Cat. No. CS-W016680
Purity ≥95%
MDL No. MFCD00800639
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄H₆O₂
Molecular Weight 86.09
Synonym(s) 3,4-epoxytetrahydrofuran
SMILES C12COCC1O2

Computational Chemistry Data

TPSA 21.76
LogP -0.216
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS02,GHS07
Signal Word : Danger	UN#: 1993
Class : 3	Packing Group : Ⅲ
Hazard Statements : H226-H315-H319-H335
Precautionary Statements : P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378-P403+P235-P501

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Other Classifications

Building Blocks Skeleton Bridge Rings compounds Other bridge ring compounds

Material Science Polymer Materials Macromolecular Monomer

Material Science Polymer/Macromolecule Reagents Monomers Epoxide Monomers

Key Words

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3,6-Dioxabicyclo[3.1.0]hexane

CAS No. 285-69-8

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