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CS-W001157 4
Total: USD 88.00

[(1,2,3-η)-2-Butenyl]chloro(tricyclohexylphosphine)palladium

  • CAS No. 307494-95-7

  • Cat. No. CS-0639653
  • Purity≥98%
  • MDL No.None
  • HazMat Fee +

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    The shipment is processed through FedEx Ground under the Limited Quantity option.

    Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

    If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

    Type
    HazMat Fee
    Excepted Quantity $0.00
    FedEx Limited Quantities Ground $0.00
    Hazmat Ground shipping $50.00+
    Inaccessible (Haz class 6.1 or 9), Domestic $68.00+
    Accessible (Haz class 3, 4, 5 or 8), Domestic $158.00+
    Inaccessible (Haz class 6.1 or 9), International $108.00+
    Accessible (Haz class 3, 4, 5 or 8), International $238.00+

    An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

    There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

[(1,2,3-η)-2-Butenyl]chloro(tricyclohexylphosphine)palladium|CS-0639653

Structure of 307494-95-7

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Description

This palladium complex features a [(1,2,3-η)-2-butene] ligand coordinated to a chloro and tricyclohexylphosphine moiety, delivering enhanced stability and reactivity in cross-coupling processes. The bulky phosphine ligand minimizes decomposition pathways, enabling efficient transformations under mild conditions. This robust catalyst facilitates C–C bond formation with high functional group tolerance, particularly effective in Suzuki-Miyaura and Negishi coupling reactions.

Application

[(1,2,3-η)-2-Butenyl]chloro(tricyclohexylphosphine)palladium serves as a robust, bench-stable precatalyst for palladium-catalyzed cross-coupling reactions. It enables efficient Suzuki-Miyaura, Stille, and Negishi couplings with excellent functional group tolerance and predictable reactivity. The tricyclohexylphosphine ligand enhances catalyst stability and facilitates rapid activation under mild conditions, making it ideal for complex molecule synthesis in medicinal chemistry and process development workflows.

General Information

  • CAS No. 307494-95-7
  • Cat. No. CS-0639653
  • Purity ≥98%
  • MDL No. None
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₂H₄₀ClPPd
  • Molecular Weight 477.40
  • Synonym(s) None
  • SMILES [Cl-][Pd+2]12([P](C3CCCCC3)(C4CCCCC4)C5CCCCC5)[CH2-][CH]1=[CH]2C

Computational Chemistry Data

  • TPSA   N/A
  • LogP   N/A
  • H_Acceptors   N/A
  • H_Donors   N/A
  • Rotatable_Bonds   N/A

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

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