Lot numbers can be found on the outside label of a product:
6-Benzyloxy-3,4-dihydro-2H-naphthalen-1-one
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CAS No. 32263-70-0
- Cat. No. CS-B1524
- Purity≥98%
- MDL No.MFCD12024333
*For research and further manufacturing use only, not for direct human use.
Structure of 32263-70-0
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General Information
- CAS No. 32263-70-0
- Cat. No. CS-B1524
- Purity ≥98%
- MDL No. MFCD12024333
- Storage 4°C
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₁₇H₁₆O₂
- Molecular Weight 252.31
- Synonym(s) 6-(Benzyloxy)-3,4-dihydro-1(2H)-naphthalenone; 6-(Benzyloxy)-3,4-dihydronaphthalene-1(2H)-one; Bdg3ef; 6-(benzyloxy)-3,4-dihydronaphthalen-1(2H)-one
- SMILES O=C1CCCC2=C1C=CC(OCC3=CC=CC=C3)=C2
Description
6-Benzyloxy-3,4-dihydro-2H-naphthalen-1-one features a benzyl ether-protected hydroxynaphthalene scaffold with enhanced stability and solubility. This bench-stable intermediate integrates readily into synthetic sequences requiring selective functionalization at the aromatic ring. The protected phenolic moiety enables orthogonal reactivity in complex molecule assembly.
Application
6-Benzyloxy-3,4-dihydro-2H-naphthalen-1-one serves as a versatile intermediate in the synthesis of substituted naphthalene derivatives and heterocyclic scaffolds. Its benzyloxy group provides orthogonal protection for phenolic functionalities, while the enone system enables Michael additions, conjugate reductions, and palladium-catalyzed coupling reactions. The compound exhibits good bench stability and facilitates straightforward purification, making it suitable for iterative synthetic sequences in medicinal chemistry and process development.
Synthesis
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Route1
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In-stock
3470-50-6 -
100-39-0 - ~96%
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In-stock
32263-70-0
References
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Legoabe, Lesetja J.; Petzer, Anel; Petzer, Jacobus P. Bioorganic and Medicinal Chemistry Letters, 2014 , vol. 24, # 12 p. 2758 - 2763
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Route2
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In-stock
3470-50-6
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100-44-7
- ~79%
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In-stock
32263-70-0
References
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Delgado; Garcia; Mauleon; Minguillon; Subirats; Feliz; Lopez; Velasco Canadian Journal of Chemistry, 1988 , vol. 66, # 3 p. 517-527
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Route3
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In-stock
1078-19-9 - ~%
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In-stock
32263-70-0
References
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Legoabe, Lesetja J.; Petzer, Anel; Petzer, Jacobus P. Bioorganic and Medicinal Chemistry Letters, 2014 , vol. 24, # 12 p. 2758 - 2763
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 26.3
- LogP 3.7846
- H_Acceptors 2
- H_Donors 0
- Rotatable_Bonds 3
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Key Words
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