Lot numbers can be found on the outside label of a product:
Methyl 6-aminopicolinate
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CAS No. 36052-26-3
- Cat. No. CS-W004981
- Purity≥97%
- MDL No.MFCD00233712
*For research and further manufacturing use only, not for direct human use.
Structure of 36052-26-3
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General Information
- CAS No. 36052-26-3
- Cat. No. CS-W004981
- Purity ≥97%
- MDL No. MFCD00233712
- Storage 4°C, protect from light
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₇H₈N₂O₂
- Molecular Weight 152.15
- Synonym(s) Methyl 6-aminopyridine-2-carboxylate
- SMILES COC(C1=CC=CC(=N1)N)=O
Description
Methyl 6-aminopicolinate features a strategically positioned amino group ortho to the ester, enabling direct conjugation and enhanced solubility in polar solvents. This electron-rich scaffold integrates readily into bioconjugation workflows and serves as a key intermediate for pharmaceutical and agrochemical synthesis under standard conditions.
Application
Methyl 6-aminopicolinate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to bioactive heterocycles and pharmaceutical intermediates. Its ortho-amino and ester functionalities offer complementary reactivity for coupling reactions, amide formation, and cyclization processes. The compound exhibits excellent bench stability and facilitates straightforward purification, making it well-suited for multi-step synthesis and process-scale applications.
Synthesis
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Route1
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67-56-1 -
In-stock
23628-31-1 - ~77%
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In-stock
36052-26-3
References
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Le Hir de Fallois, Loic Patrick; Lee, Hyoung Ik; Wilkinson, Douglas Edward; Beck, Brent Christopher Patent: US2011/152312 A1, 2011 ; Location in patent: Page/Page column 40 ;
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Route2
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67-56-1
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26893-72-1 - ~65%
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In-stock
36052-26-3
References
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Ontoria, Jesus M.; Martin Hernando, Jose I.; Malancona, Savina; Attenni, Barbara; Stansfield, Ian; Conte, Immacolata; Ercolani, Caterina; Habermann, Joerg; Ponzi, Simona; Di Filippo, Marcello; Koch, Uwe; Rowley, Michael; Narjes, Frank Bioorganic and Medicinal Chemistry Letters, 2006 , vol. 16, # 15 p. 4026 - 4030
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Route3
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26893-72-1
- ~60%
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In-stock
36052-26-3
References
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F. HOFFMANN-LA ROCHE AG; BAUMANN, Karlheinz; FLOHR, Alexander; GOETSCHI, Erwin; GREEN, Luke; JOLIDON, Synese; KNUST, Henner; LIMBERG, Anja; LUEBBERS, Thomas; THOMAS, Andrew Patent: WO2011/101304 A2, 2011 ; Location in patent: Page/Page column 91-92 ; WO 2011/101304 A2
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 65.21
- LogP 0.4504
- H_Acceptors 4
- H_Donors 1
- Rotatable_Bonds 1
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