4-Bromo-N,N-diphenylaniline

Name: 4-Bromo-N,N-diphenylaniline
Brand: ChemScene
Availability: InStock
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CAS No. 36809-26-4
Cat. No. CS-W002829
Purity≥97%
MDL No.MFCD01851266

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 36809-26-4

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Description

4-Bromo-N,N-diphenylaniline features a bromine substituent at the para position of a triarylamine scaffold, delivering enhanced electron-withdrawing character and improved stability under standard conditions. This bench-stable compound integrates readily into cross-coupling reactions and serves as a robust building block for functionalized aryl materials in organic electronics and pharmaceutical development.

Application

4-Bromo-N,N-diphenylaniline serves as a versatile building block in cross-coupling chemistry, enabling efficient Pd-catalyzed transformations such as Suzuki-Miyaura and Buchwald-Hartwig reactions. The bromo group facilitates reliable C–C and C–N bond formation under standard conditions, while the diphenylamino moiety provides steric and electronic stability. This compound exhibits excellent bench stability, simplifies purification, and functions effectively in the construction of biaryl and heterocyclic scaffolds relevant to pharmaceutical and materials research.

General Information

CAS No. 36809-26-4
Cat. No. CS-W002829
Purity ≥97%
MDL No. MFCD01851266
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₈H₁₄BrN
Molecular Weight 324.21
Synonym(s) benzene, 1-bromo-4-(diphenylmethyl)-; 4-Bromo-N,N-diphenylaniline
SMILES Brc1ccc(cc1)N(c1ccccc1)c1ccccc1

Computational Chemistry Data

TPSA 3.24
LogP 5.9189
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 3

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H317-H319-H335-H413
Precautionary Statements : P261-P264-P270-P271-P272-P273-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

Quality Control

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Material Science Material Composite Block Small Molecule Semiconductor Synthesis Building Block

Material Science Solar Cell Materials Donor Intermediate DI

Material Science Material Building Blocks Small Molecule Semiconductor Building Blocks Tertiary Arylamines

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4-Bromo-N,N-diphenylaniline

CAS No. 36809-26-4

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