5,10,15,20-tetrakis(p-chlorophenyl)porphyrin iron(III) chloride

Name: 5,10,15,20-tetrakis(p-chlorophenyl)porphyrin iron(III) chloride
Brand: ChemScene
Availability: InStock
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CAS No. 36965-70-5
Cat. No. CS-0160751
Purity≥95%
MDL No.MFCD31537210

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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5,10,15,20-tetrakis(p-chlorophenyl)porphyrin iron(III) chloride|CS-0160751

Structure of 36965-70-5

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General Information

CAS No. 36965-70-5
Cat. No. CS-0160751
Purity ≥95%
MDL No. MFCD31537210
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄₄H₂₄Cl₅FeN₄
Molecular Weight 841.80
Synonym(s) meso-Tetrakis(4-chlorophenyl)porphyrin-Fe(III)chloride
SMILES ClC=1C=CC(=CC1)C2=C3C=CC=4C(C=5C=CC(Cl)=CC5)=C6C=CC7=C(C8=CC=C(Cl)C=C8)C=9C=CC%10=C(C%11=CC=C(Cl)C=C%11)C%12=CC=C2[N-]%12[Fe+3]([Cl-])([N]34)([N]%109)[N-]67

Description

5,10,15,20-Tetrakis(p-chlorophenyl)porphyrin iron(III) chloride features a robust porphyrin core with four para-chlorophenyl substituents that enhance solubility and electronic stability. The iron(III) center enables catalytic activity in oxidation reactions, while the electron-withdrawing chloro groups tune redox potential. This complex exhibits high thermal resilience and is well-suited for use in synthetic and materials applications requiring durable transition metal coordination.

Application

5,10,15,20-Tetrakis(p-chlorophenyl)porphyrin iron(III) chloride serves as a robust, bench-stable catalyst for oxidation reactions and functions as a well-characterized metalloporphyrin model for studying heme enzyme mimetics. Its four p-chlorophenyl groups enhance solubility and stability in organic media, facilitating use in catalytic oxidations, epoxidations, and C–H functionalization under mild conditions.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

Other Classifications

Catalysts and Ligands Catalysts Transition Metal Catalysts Fe Catalysts

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Catalysis Non-Precious Metal Catalysis

Catalysis Asymmetric Synthesis Chiral Catalysts, Chiral Ligands, Chiral Reagents Chiral Catalysts (Other)

Catalysis C-H Activation Iron Compounds

Catalysis Compounds by Element Classes Metal Compounds Transition Metal Compounds

Catalysis Cross-coupling Reaction using Transition Metal Catalysts Iron Catalysts

Catalysis Transition Elements Iron

Key Words

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5,10,15,20-tetrakis(p-chlorophenyl)porphyrin iron(III) chloride

CAS No. 36965-70-5

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