2-Bromo-1-methoxy-3-methylbenzene

Name: 2-Bromo-1-methoxy-3-methylbenzene
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CAS No. 38197-43-2
Cat. No. CS-0137291
Purity≥97%
MDL No.MFCD14705101

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2-Bromo-1-methoxy-3-methylbenzene|CS-0137291

Structure of 38197-43-2

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Description

This methoxy-substituted aryl bromide features a methyl group at the para position relative to the bromine, enabling efficient palladium-catalyzed cross-coupling reactions. The electron-donating methoxy and methyl groups enhance reactivity while maintaining stability under standard conditions.

Application

2-Bromo-1-methoxy-3-methylbenzene serves as a versatile aryl building block in cross-coupling reactions, enabling efficient construction of biaryl and heteroaryl architectures. Its bromine functionality facilitates reliable Suzuki, Stille, and Negishi couplings under standard conditions, while the methoxy and methyl groups provide orthogonal directing effects and moderate electron-donating character. The compound exhibits good bench stability and is amenable to purification by silica gel chromatography, making it well-suited for iterative synthetic sequences in medicinal chemistry and materials science applications.

General Information

CAS No. 38197-43-2
Cat. No. CS-0137291
Purity ≥97%
MDL No. MFCD14705101
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₉BrO
Molecular Weight 201.06
Synonym(s) 2-Bromo-3-methoxytoluene
SMILES CC1=C(Br)C(OC)=CC=C1

Computational Chemistry Data

TPSA 9.23
LogP 2.76612
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Bromo-1-methoxy-3-methylbenzene

CAS No. 38197-43-2

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