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CS-W001157 4
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Tetrabutylammonium tetrafluoroborate

  • CAS No. 429-42-5

  • Cat. No. CS-0022349
  • Molecule weight329.27
  • Purity≥97%
  • MDL No.MFCD00011634

*For research and further manufacturing use only, not for direct human use.

Tetrabutylammonium tetrafluoroborate|CS-0022349

Structure of 429-42-5

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General Information

  • CAS No. 429-42-5
  • Cat. No. CS-0022349
  • Purity ≥97%
  • MDL No. MFCD00011634
  • Storage -20°C, sealed storage, away from moisture
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₆H₃₆BF₄N
  • Molecular Weight 329.27
  • Synonym(s) Tetra-n-butylammonium (tetrafluoroborate)
  • SMILES [F-][B+3]([F-])([F-])[F-].CCCC[N+](CCCC)(CCCC)CCCC

Description

Tetrabutylammonium tetrafluoroborate is used as an electrolyte for the series of arylketone synthesis. Tetrabutylammonium tetrafluoroborate (TBATFB) is a phase transfer catalyst. It can be synthesized by the reaction between 30% aqueous solution of tetrafluoroboric acid and 40% aqueous solution of tetrabutylamonium hydroxide. Tetrabutylammonium tetrafluoroborate acts as an electrolyte and inhibits the self-assembly of alkylthiosulfate on gold.Tetrabutylammonium tetrafluoroborate may be used in the following studies: As supporting electrolyte in the voltammetric determination of (9)-tetrahydrocannabinol ((9)-THC). Synthesis of biologically relevant macrolactones, Sansalvamide A. As supporting electrolyte in the determination of the oxidation and reduction potentials of 5,10,15,20-tetra[3-(3-trifluoromethyl)phenoxy]porphyrin by cyclic voltammetry. Preparation of 1:1 adduct with 1,10-phenanthroline.Used to prepare other tetrabutylammonium salts in aqueous solutions. As electrolyte additive in the synthesis of conducting poly(thiophenes).

Synthesis

  • Route1

    References

    • LONZA LTD; OTT, Lothar; RIJKSEN, Christiaan; ELLINGER, Stefan; SIEVERT, Katharina; HARLOFF, Jörg; SCHULZ, Axel Patent: WO2014/29834 A1, 2014 ; Location in patent: Page/Page column 9; 10 ;
  • Route2
    • Tetrabutylammonium (fluoride) (solution),1M in THF|CS-W020033
      429-41-4
    • ~75%
    • In-stock
      Tetrabutylammonium tetrafluoroborate|CS-0022349
      429-42-5

    References

    • Tembwe, Inonge; Ngila, J. Catherine; Kgarebe, Boitumelo; Darkwa, James; Iwuoha, Emmanuel Electrochimica Acta, 2010 , vol. 55, # 14 p. 4314 - 4318
  • Route3
    • null|null
      1375484-85-7
    • ~0%
    • Fluorotrichloroethylene|CS-0760165
      359-29-5
    • null|null
      1375485-03-2
    • In-stock
      Tetrabutylammonium tetrafluoroborate|CS-0022349
      429-42-5

    References

    • Bardin, Vadim V.; Adonin, Nicolay Yu.; Frohn, Hermann-Josef Zeitschrift fur Anorganische und Allgemeine Chemie, 2012 , vol. 638, # 3-4 p. 565 - 579

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05,GHS07
Signal Word : Danger
UN#: 1759
Class : 8
Packing Group : Ⅲ
Hazard Statements : H302-H315-H318-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

  • TPSA   N/A
  • LogP   N/A
  • H_Acceptors   N/A
  • H_Donors   N/A
  • Rotatable_Bonds   N/A

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