3-Bromo-4-iodoanisole

Name: 3-Bromo-4-iodoanisole
Brand: ChemScene
Availability: InStock
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CAS No. 466639-53-2
Cat. No. CS-0028750
Purity≥96%
MDL No.MFCD12547848

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Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

Structure of 466639-53-2

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Description

3-Bromo-4-iodoanisole features a strategically positioned bromo and iodo substituent on an anisole scaffold, enabling selective cross-coupling reactions. The methoxy group enhances solubility and directs regiochemistry, while the halogens offer orthogonal reactivity for sequential functionalization under standard palladium catalysis.

Application

3-Bromo-4-iodoanisole serves as a versatile biaryl building block in palladium-catalyzed cross-coupling reactions, enabling efficient synthesis of substituted aryl scaffolds. The ortho-bromo and para-iodo substituents offer complementary reactivity for sequential functionalization, while the methoxy group provides electronic modulation and enhanced stability under standard coupling conditions. This compound facilitates precise control in complex molecule assembly, particularly in pharmaceutical and agrochemical research workflows.

General Information

CAS No. 466639-53-2
Cat. No. CS-0028750
Purity ≥96%
MDL No. MFCD12547848
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₆BrIO
Molecular Weight 312.93
Synonym(s) Benzene, 2-bromo-1-iodo-4-methoxy-
SMILES COC1=CC=C(I)C(Br)=C1

Computational Chemistry Data

TPSA 9.23
LogP 3.0623
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Bromo-4-iodoanisole

CAS No. 466639-53-2

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