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CS-W001157 4
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Allyl 2,2,2-trichloroacetimidate

  • CAS No. 51479-73-3

  • Cat. No. CS-0157985
  • Molecule weight202.47
  • Purity≥97%
  • MDL No.MFCD00190710

*For research and further manufacturing use only, not for direct human use.

Allyl 2,2,2-trichloroacetimidate|CS-0157985

Structure of 51479-73-3

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General Information

  • CAS No. 51479-73-3
  • Cat. No. CS-0157985
  • Purity ≥97%
  • MDL No. MFCD00190710
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₅H₆Cl₃NO
  • Molecular Weight 202.47
  • Synonym(s) 2,2,2-Trichloroacetimidic Acid Allyl Ester
  • SMILES C=CCOC(=N)C(Cl)(Cl)Cl

Description

Allyl 2,2,2-trichloroacetimidate serves as a stable, moisture-tolerant glycosyl donor featuring a trichloromethyl-imidate linkage. This reagent enables efficient glycosylation under mild conditions, delivering high stereoselectivity in the formation of β-glycosidic bonds. The allyl group facilitates subsequent manipulation via cross-coupling or deprotection, streamlining complex oligosaccharide synthesis.

Synthesis

  • Route1
    • null|null
      107-18-6
    • null|null
      545-06-2
    • ~87%
    • In-stock
      Allyl 2,2,2-trichloroacetimidate|CS-0157985
      51479-73-3

    References

    • Gajdosikova, Eva; Martinkova, Miroslava; Gonda, Jozef; Conka, Patrik Molecules, 2008 , vol. 13, # 11 p. 2837 - 2847

Safety Information

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GHS Pictogram :
GHS No : GHS05
Signal Word : Danger
UN#: 1760
Class : 8
Packing Group : Ⅲ
Hazard Statements : H302-H315-H318-H335
Precautionary Statements : P280-P302+P352-P330

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Computational Chemistry Data

  • TPSA   33.08
  • LogP   2.53647
  • H_Acceptors   2
  • H_Donors   1
  • Rotatable_Bonds   2

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