6,6'-Dichloro-2,2'-bipyridine

Name: 6,6'-Dichloro-2,2'-bipyridine
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 53344-72-2
Cat. No. CS-0096462
Purity≥96%
MDL No.MFCD11042483

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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6,6'-Dichloro-2,2'-bipyridine|CS-0096462

Structure of 53344-72-2

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Description

6,6'-Dichloro-2,2'-bipyridine is a sterically hindered bipyridine ligand featuring two chlorine substituents at the 6 and 6' positions. This electron-deficient scaffold enhances metal coordination stability in transition metal complexes, particularly in catalytic systems requiring robust ligand frameworks. The dichloro substitution improves solubility in organic solvents and supports efficient complexation under standard conditions.

Application

6,6'-Dichloro-2,2'-bipyridine serves as a versatile ligand scaffold in transition metal catalysis, enabling robust coordination with palladium, ruthenium, and copper complexes. Its electron-deficient nature enhances catalyst stability and modulates reactivity in cross-coupling processes. The dichloro substitution provides improved bench stability and facilitates purification via standard chromatographic methods. Functions effectively in C–H activation, cyclization, and heterocycle synthesis applications.

General Information

CAS No. 53344-72-2
Cat. No. CS-0096462
Purity ≥96%
MDL No. MFCD11042483
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₆Cl₂N₂
Molecular Weight 225.07
Synonym(s) 2-chloro-6-(6-chloropyridin-2-yl)pyridine
SMILES ClC1=CC=CC(C2=NC(Cl)=CC=C2)=N1

Computational Chemistry Data

TPSA 25.78
LogP 3.4504
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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6,6'-Dichloro-2,2'-bipyridine

CAS No. 53344-72-2

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