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CS-W001157 4
Total: USD 88.00

(2-Aminophenyl)methanol

  • CAS No. 5344-90-1

  • Cat. No. CS-W004705
  • Purity≥98%
  • MDL No.MFCD00007749

*For research and further manufacturing use only, not for direct human use.

(2-Aminophenyl)methanol|CS-W004705

Structure of 5344-90-1

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General Information

  • CAS No. 5344-90-1
  • Cat. No. CS-W004705
  • Purity ≥98%
  • MDL No. MFCD00007749
  • Storage 4°C, protect from light
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₇H₉NO
  • Molecular Weight 123.16
  • Synonym(s) 2-Hydroxymethylaniline
  • SMILES OCC1=CC=CC=C1N

Description

2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde.2-Aminobenzyl alcohol was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.

Synthesis

  • Route1

    References

    • Li, Nai-Hong; Frechet, Jean M. J. Journal of the Chemical Society, Chemical Communications, 1985 , # 16 p. 1100 - 1101
  • Route2
    • null|null
      118-92-3
    • ~99%
    • In-stock
      (2-Aminophenyl)methanol|CS-W004705
      5344-90-1

    References

    • Jia, Min-Qiang; You, Shu-Li ACS Catalysis, 2013 , vol. 3, # 4 p. 622 - 624
  • Route3

    References

    • Vernekar, Amit A.; Patil, Sagar; Bhat, Chinmay; Tilve, Santosh G. RSC Advances, 2013 , vol. 3, # 32 p. 13243 - 13250

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   46.25
  • LogP   0.7611
  • H_Acceptors   2
  • H_Donors   2
  • Rotatable_Bonds   1

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