2-Bromo-3-methylaniline

Name: 2-Bromo-3-methylaniline
Brand: ChemScene
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CAS No. 54879-20-8
Cat. No. CS-W007900
Purity≥97%
MDL No.MFCD06411367

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Description

2-Bromo-3-methylaniline features a bromine atom at the ortho position relative to the amino group and a methyl substituent at the adjacent carbon, creating a sterically hindered, electron-rich aromatic system. This configuration enhances regioselectivity in coupling reactions and improves stability under standard bench conditions. The compound serves as a key building block for functionalized anilines in pharmaceutical synthesis and agrochemical development.

Application

2-Bromo-3-methylaniline serves as a valuable building block in medicinal chemistry and agrochemical synthesis, enabling direct functionalization at the aniline ring. Its ortho-bromo substituent facilitates palladium-catalyzed cross-coupling reactions, while the meta-methyl group enhances metabolic stability and modulates electronic properties. The compound exhibits good bench stability and is compatible with standard purification techniques, making it well-suited for multi-step synthesis workflows.

General Information

CAS No. 54879-20-8
Cat. No. CS-W007900
Purity ≥97%
MDL No. MFCD06411367
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₈BrN
Molecular Weight 186.05
Synonym(s) Benzenamine, 2-bromo-3-methyl-
SMILES NC1=CC=CC(C)=C1Br

Computational Chemistry Data

TPSA 26.02
LogP 2.33972
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 0

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H317
Precautionary Statements : P261-P264-P270-P272-P280-P302+P352-P330-P362+P364-P501

Quality Control

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Bromo-3-methylaniline

CAS No. 54879-20-8

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