2-(3-Bromopropyl)-1,3-dioxolane

Name: 2-(3-Bromopropyl)-1,3-dioxolane
Brand: ChemScene
Availability: InStock
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CAS No. 62563-07-9
Cat. No. CS-0159608
Purity≥95%
MDL No.MFCD09868694

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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2-(3-Bromopropyl)-1,3-dioxolane|CS-0159608

Structure of 62563-07-9

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General Information

CAS No. 62563-07-9
Cat. No. CS-0159608
Purity ≥95%
MDL No. MFCD09868694
Storage -20°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₁₁BrO₂
Molecular Weight 195.05
Synonym(s) 4-Bromobutyraldehyde Ethylene Acetal
SMILES BrCCCC1OCCO1

Description

This dioxolane derivative features a bromopropyl chain enabling direct functionalization in synthetic sequences. The cyclic acetal scaffold enhances stability and solubility, while the terminal bromide supports efficient coupling reactions under mild conditions. A reliable handle for building complex architectures in organic synthesis and medicinal chemistry workflows.

Application

2-(3-Bromopropyl)-1,3-dioxolane serves as a versatile bifunctional building block for the synthesis of complex heterocycles and bioactive molecules. The bromide functionality enables efficient alkylation or transition-metal-catalyzed coupling reactions, while the 1,3-dioxolane ring provides stability and orthogonality under basic conditions. This compound facilitates the construction of pharmacophoric scaffolds with predictable reactivity, offering reliable access to intermediates in medicinal chemistry campaigns.

Synthesis

Route1
- In-stock
  
  2969-81-5
- In-stock
  
  107-21-1
- ~86%
- In-stock
  
  62563-07-9
References
- Varseev, Georgy N.; Maier, Martin E. Organic Letters, 2005 , vol. 7, # 18 p. 3881 - 3884
Route2
- 38694-47-2
- In-stock
  
  107-21-1
- ~89%
- In-stock
  
  62563-07-9
References
- Wenkert, David; Ferguson, Stephen B.; Porter, Barry; Qvarnstrom, Anders; McPhail, Andrew T. Journal of Organic Chemistry, 1985 , vol. 50, # 21 p. 4114 - 4119

Safety Information

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GHS Pictogram :	GHS No : GHS02
Signal Word : Danger	UN#: 1993
Class : 3	Packing Group : Ⅲ
Hazard Statements : H227
Precautionary Statements : P210-P280-P501

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Computational Chemistry Data

TPSA 18.46
LogP 1.5344
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 3

Other Classifications

Building Blocks Skeleton Aliphatic heterocycle compounds Dioxolane compounds

Key Words

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2-(3-Bromopropyl)-1,3-dioxolane

CAS No. 62563-07-9

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