Methyl 5-bromo-2,3-dihydro-1H-indene-2-carboxylate

Name: Methyl 5-bromo-2,3-dihydro-1H-indene-2-carboxylate
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CAS No. 628732-09-2
Cat. No. CS-0343617
Purity≥95%
MDL No.MFCD17926572

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FedEx Limited Quantities Ground	$0.00
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Methyl 5-bromo-2,3-dihydro-1H-indene-2-carboxylate|CS-0343617

Structure of 628732-09-2

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General Information

CAS No. 628732-09-2
Cat. No. CS-0343617
Purity ≥95%
MDL No. MFCD17926572
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₁H₁₁BrO₂
Molecular Weight None
Synonym(s) 1H-Indene-2-carboxylic acid, 5-bromo-2,3-dihydro-, methyl ester
SMILES O=C(C1CC2=C(C=C(Br)C=C2)C1)OC

Description

Methyl 5-bromo-2,3-dihydro-1H-indene-2-carboxylate features a brominated indene core with a pendant methyl ester, enabling direct functionalization at the electron-deficient C5 position. This bench-stable scaffold integrates readily into transition-metal-catalyzed coupling cascades and serves as a key intermediate in synthesizing bioactive heterocycles and pharmaceutical analogs.

Application

Methyl 5-bromo-2,3-dihydro-1H-indene-2-carboxylate serves as a versatile building block in synthetic organic chemistry, enabling palladium-catalyzed cross-coupling reactions due to its stable bromo substituent. The dihydroindene core provides rigidity and spatial control, while the ester functionality allows for further transformations such as hydrolysis or reduction. Its bench-stable nature and compatibility with standard reaction conditions make it well-suited for applications in medicinal chemistry and materials science.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 26.3
LogP 2.3369
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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Methyl 5-bromo-2,3-dihydro-1H-indene-2-carboxylate

CAS No. 628732-09-2

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