4-Bromo-2-methoxy-1-phenylmethoxybenzene

Name: 4-Bromo-2-methoxy-1-phenylmethoxybenzene
Brand: ChemScene
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CAS No. 63057-72-7
Cat. No. CS-0061925
Purity≥97%
MDL No.MFCD00092521

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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4-Bromo-2-methoxy-1-phenylmethoxybenzene|CS-0061925

Structure of 63057-72-7

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Description

4-Bromo-2-methoxy-1-phenylmethoxybenzene features a strategically positioned bromine atom and a methoxy group flanking a phenylmethoxy substituent, enabling selective cross-coupling reactions. This electron-rich aromatic scaffold integrates readily into complex molecular architectures under standard conditions.

Application

4-Bromo-2-methoxy-1-phenylmethoxybenzene serves as a versatile building block in cross-coupling reactions, enabling efficient construction of biaryl scaffolds. Its ortho-methoxy and para-bromo substituents provide orthogonal reactivity for sequential functionalization. The phenylmethoxy group offers stability and facilitates purification, while the bromine center supports reliable Pd-catalyzed coupling under standard conditions. This compound functions effectively in the synthesis of complex pharmaceutical intermediates and functionalized aromatic systems.

General Information

CAS No. 63057-72-7
Cat. No. CS-0061925
Purity ≥97%
MDL No. MFCD00092521
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₄H₁₃BrO₂
Molecular Weight 293.16
Synonym(s) 1-(Benzyloxy)-4-bromo-2-methoxybenzene
SMILES COC1=C(C=CC(=C1)Br)OCC2=CC=CC=C2

Computational Chemistry Data

TPSA 18.46
LogP 4.0367
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 4

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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4-Bromo-2-methoxy-1-phenylmethoxybenzene

CAS No. 63057-72-7

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