3-Bromo-1,10-phenanthroline

Name: 3-Bromo-1,10-phenanthroline
Brand: ChemScene
Availability: InStock
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CAS No. 66127-01-3
Cat. No. CS-W004585
Purity≥98%
MDL No.MFCD08276287

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

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Structure of 66127-01-3

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Description

3-Bromo-1,10-phenanthroline is a bench-stable, electron-deficient heteroaromatic ligand featuring a bromine substituent at the 3-position. This substitution enhances its utility in transition metal catalysis and coordination chemistry, enabling efficient coupling reactions and stable complex formation. The rigid planar structure facilitates π-stacking interactions and promotes predictable binding geometry in metal complexes.

Application

3-Bromo-1,10-phenanthroline serves as a versatile ligand scaffold in transition metal catalysis, enabling palladium- and copper-catalyzed cross-coupling reactions. Its bromine substituent facilitates further functionalization via standard coupling protocols, while the rigid aromatic framework provides strong metal chelation. The compound exhibits excellent bench stability and ease of purification, making it suitable for iterative synthesis and catalyst development in medicinal chemistry and materials science applications.

General Information

CAS No. 66127-01-3
Cat. No. CS-W004585
Purity ≥98%
MDL No. MFCD08276287
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₇BrN₂
Molecular Weight 259.10
Synonym(s) 3-BROMO-1,10-PHENTHROLINE
SMILES BrC1=CC2=CC=C(C=CC=N3)C3=C2N=C1

Computational Chemistry Data

TPSA 25.78
LogP 3.5455
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Catalysts and Ligands Ligands Pyridine Ligands Phenanthroline Ligands

Material Science Material Building Blocks Ligands for Functional Metal Complexes Phenanthroline Ligands

Catalysis Nitrogen-Donor Ligands Pyridine Ligands

Catalysis Nitrogen-Donor Ligands Phenanthroline Ligands

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3-Bromo-1,10-phenanthroline

CAS No. 66127-01-3

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