(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(III) p-toluenesulfonate

Name: (1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(III) p-toluenesulfonate
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 672306-06-8
Cat. No. CS-0086868
Purity≥98%
MDL No.MFCD11973801

HazMat Fee +

HazMat Fee

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it. There is a HazMat shipping fee for each item that qualifies as a dangerous good, except in the following scenarios:

The shipment is processed through FedEx Ground under the Limited Quantity option.

Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(III) p-toluenesulfonate|CS-0086868

Structure of 672306-06-8

Size

Price

Quantity

* Please select Quantity before adding items.

Description

This cobalt(III) complex features a chiral diamine ligand with bulky di-t-butylsalicylidene groups, delivering high enantioselectivity in catalytic transformations. The p-toluenesulfonate counterion enhances solubility and stability under standard conditions, enabling efficient asymmetric synthesis.

Application

(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(III) p-toluenesulfonate serves as a chiral cobalt(III) complex enabling enantioselective epoxidation and C–H functionalization reactions. Its steric shielding from bulky di-t-butyl groups enhances stereocontrol, while the p-toluenesulfonate counterion ensures solubility and operational stability. The complex exhibits robust bench stability and facilitates high enantiomeric excess in standard oxidation protocols.

General Information

CAS No. 672306-06-8
Cat. No. CS-0086868
Purity ≥98%
MDL No. MFCD11973801
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄₃H₅₉CoN₂O₅S
Molecular Weight 774.94
Synonym(s) CoIII(t-Bu-salen)-OTs
SMILES CC(C)(C)C1=CC(C(C)(C)C)=C([O-][Co+3]23[O-]C4=C(C=C(C(C)(C)C)C=C4C(C)(C)C)C=[N]52)C(C=[N]3[C@@H]6[C@@H]5CCCC6)=C1.CC7=CC=C(S(=O)([O-])=O)C=C7

Computational Chemistry Data

TPSA 100.38
LogP 10.3086
H_Acceptors 7
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

Quality Control

To search for quality control of cas , please enter both the product number and the lot/batch number.

Key Words

672306-06-8 sigma672306-06-8 manufacturer672306-06-8 price672306-06-8 structure672306-06-8 SDSbuy 672306-06-8672306-06-8 supplier672306-06-8 uses672306-06-8 molecular weightprice of 672306-06-8672306-06-8 chemical name formula of 672306-06-8

Salutation:	*Country or Region:
*Applicant Name:	*Organization Name:
*Email Address:	Quantity:
CAS NO. :	Product Name:
Remarks:
Upload Pictures

CAS.No.		Product Name
Applicant Name *		Email Address *
Phone Number *		Organization Name*
Country or Region*		Quantity*
Remarks:

Product Name:
Cat. No.: .		CAS NO. :
Quantity:

(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(III) p-toluenesulfonate

CAS No. 672306-06-8

Recommended Products