(4-Bromo-2,6-difluorophenyl)amine

Name: (4-Bromo-2,6-difluorophenyl)amine
Brand: ChemScene
Availability: InStock
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CAS No. 67567-26-4
Cat. No. CS-M3537
Purity≥98%
MDL No.MFCD00013389

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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(4-Bromo-2,6-difluorophenyl)amine|CS-M3537

Structure of 67567-26-4

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General Information

CAS No. 67567-26-4
Cat. No. CS-M3537
Purity ≥98%
MDL No. MFCD00013389
Storage RT, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₄BrF₂N
Molecular Weight 208.00
Synonym(s) 2,6-Difluoro-4-bromoaniline; 4-Bromo-2,6-difluoroaniline; 4-Bromo-2,6-difluoro
SMILES NC1=C(F)C=C(Br)C=C1F

Description

4-Bromo-2,6-difluoroaniline was used in synthesis of:ammonium 5-bromo-7-fluorobenzo-2-oxa-1,3-diazole-4-sulphonate, fluorogenic derivatizating reagent for the determination of aminothiols by HPLColefin tolanes1-(4-amino-3,5-difluoro)-2-(4-butyloxyphenyl)ethyne4-n-butyloxy-3,5-difluoroterphenyl-4-amine4-(3-methylbut-1-yn-3-ol)-2,6-difluoroaniline

Application

(4-Bromo-2,6-difluorophenyl)amine serves as a versatile building block for the synthesis of pharmaceutical intermediates and functional materials. Its ortho-fluoro substituents enable palladium-catalyzed cross-coupling reactions, while the bromo group provides a reliable handle for further diversification. The molecule exhibits excellent bench stability and facilitates efficient purification, making it well-suited for multi-step synthetic sequences in medicinal chemistry and process development.

Synthesis

Route1
- In-stock
  
  5509-65-9
- ~89%
- In-stock
  
  67567-26-4
References
- JANSSEN PHARMACEUTICA N.V.; ARTS, Frank, Xavier, Jozef, Herwig Patent: WO2006/15985 A1, 2006 ; Location in patent: Page/Page column 54 ;
Route2
- In-stock
  
  289-95-2
- In-stock
  
  5509-65-9
- ~%
- In-stock
  
  67567-26-4
References
- US5200110 A1, ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302+H312+H332-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 26.02
LogP 2.3095
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Fluoride

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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(4-Bromo-2,6-difluorophenyl)amine

CAS No. 67567-26-4

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