Methyl 5-bromo-2-naphthoate

Name: Methyl 5-bromo-2-naphthoate
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CAS No. 67878-76-6
Cat. No. CS-0041311
Purity≥98%
MDL No.MFCD08275021

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Description

Methyl 5-bromo-2-naphthoate is a bench-stable, moisture-tolerant naphthalene derivative featuring a bromine atom at the 5-position and a methyl ester group at the 2-position. This combination enables direct functionalization in cross-coupling reactions and facilitates downstream derivatization in synthetic organic chemistry workflows.

Application

Methyl 5-bromo-2-naphthoate serves as a versatile building block in synthetic organic chemistry, enabling palladium-catalyzed cross-coupling reactions due to its well-defined bromo functionality at the 5-position of the naphthalene core. The methyl ester group provides orthogonal reactivity for subsequent transformations, while the aromatic scaffold offers inherent stability and compatibility with standard bench-scale protocols. This compound facilitates efficient access to substituted naphthoate derivatives used in pharmaceutical intermediates and functional materials.

General Information

CAS No. 67878-76-6
Cat. No. CS-0041311
Purity ≥98%
MDL No. MFCD08275021
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₉BrO₂
Molecular Weight 265.10
Synonym(s) PO-20100107-P-548
SMILES O=C(OC)C1=CC=C2C(Br)=CC=CC2=C1

Computational Chemistry Data

TPSA 26.3
LogP 3.3889
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Naphthalene compounds

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Methyl 5-bromo-2-naphthoate

CAS No. 67878-76-6

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