2-Bromo-4-chlorophenol

Name: 2-Bromo-4-chlorophenol
Brand: ChemScene
Availability: InStock
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CAS No. 695-96-5
Cat. No. CS-W019546
Purity≥96%
MDL No.MFCD00002319

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

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Structure of 695-96-5

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Description

2-Bromo-4-chlorophenol features a phenolic hydroxyl group flanked by bromo and chloro substituents at the 2- and 4-positions, respectively. This electron-deficient aromatic system enables direct functionalization in cross-coupling reactions and serves as a key intermediate in pharmaceutical and agrochemical synthesis. The compound exhibits enhanced stability under standard bench conditions.

Application

2-Bromo-4-chlorophenol serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling efficient functionalization via Suzuki-Miyaura and Stille coupling reactions. Its orthogonal halogen reactivity facilitates sequential transformations, while the phenolic hydroxyl group supports derivatization and metal complexation. The compound exhibits good bench stability and is readily purified by recrystallization or column chromatography, making it well-suited for scalable synthetic workflows.

General Information

CAS No. 695-96-5
Cat. No. CS-W019546
Purity ≥96%
MDL No. MFCD00002319
Storage RT, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₄BrClO
Molecular Weight None
Synonym(s) Phenol, 2-bromo-4-chloro- (8CI)(9CI); 2-Bromo-4-chlorophenol
SMILES OC1=CC=C(Cl)C=C1Br

Computational Chemistry Data

TPSA 20.23
LogP 2.8081
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 0

Safety Information

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GHS Pictogram :	GHS No : GHS06
Signal Word : Danger	UN#: 2020
Class : 6.1	Packing Group : Ⅲ
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362-P405-P501

Quality Control

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Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Bromo-4-chlorophenol

CAS No. 695-96-5

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