2-Chloro-4-iodoanisole

Name: 2-Chloro-4-iodoanisole
Brand: ChemScene
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CAS No. 75676-72-1
Cat. No. CS-0044522
Purity≥97%
MDL No.MFCD15527196

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

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Structure of 75676-72-1

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Description

2-Chloro-4-iodoanisole features a strategically positioned chloro and iodo substituent on an aromatic ring, enabling selective cross-coupling reactions. The methoxy group enhances solubility and directs regiochemistry in palladium-catalyzed transformations. This bench-stable compound serves as a key intermediate in the synthesis of functionalized aryl building blocks for pharmaceutical and materials applications.

Application

2-Chloro-4-iodoanisole serves as a versatile building block in cross-coupling reactions, enabling efficient construction of biaryl scaffolds under Pd-catalyzed conditions. The ortho-chloro and para-iodo substituents provide complementary reactivity for sequential functionalization, while the methoxy group offers moderate electronic stabilization and enhanced solubility. Bench-stable and readily purified by column chromatography, it facilitates reliable synthesis of complex heterocycles and pharmaceutical intermediates.

General Information

CAS No. 75676-72-1
Cat. No. CS-0044522
Purity ≥97%
MDL No. MFCD15527196
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₆ClIO
Molecular Weight 268.48
Synonym(s) 2-Chloro-4-iodo-1-methoxybenzene
SMILES COC1=CC=C(I)C=C1Cl

Computational Chemistry Data

TPSA 9.23
LogP 2.9532
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Chloro-4-iodoanisole

CAS No. 75676-72-1

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