tert-Butyl 8-bromooctanoate

Name: tert-Butyl 8-bromooctanoate
Brand: ChemScene
Availability: InStock
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CAS No. 77383-17-6
Cat. No. CS-0162715
Purity≥95%
MDL No.MFCD27928608

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 77383-17-6

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Description

tert-Butyl 8-bromooctanoate features a brominated aliphatic chain tethered to a sterically hindered tert-butyl ester, enabling stable incorporation of reactive halogen handles in synthetic workflows. This robust scaffold facilitates efficient cross-coupling and functional group manipulation under standard conditions.

Application

tert-Butyl 8-bromooctanoate serves as a versatile bifunctional building block in synthetic organic chemistry, enabling efficient access to γ- and δ-functionalized carbonyl compounds. The bromide moiety facilitates palladium-catalyzed cross-coupling reactions, while the ester group supports selective reduction or nucleophilic substitution. Its tert-butyl protection offers enhanced bench stability and simplifies purification, making it well-suited for iterative synthesis of complex aliphatic scaffolds and functionalized intermediates.

General Information

CAS No. 77383-17-6
Cat. No. CS-0162715
Purity ≥95%
MDL No. MFCD27928608
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₂₃BrO₂
Molecular Weight 279.22
Synonym(s) None
SMILES O=C(OC(C)(C)C)CCCCCCCBr

Computational Chemistry Data

TPSA 26.3
LogP 4.0636
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 7

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Fatty chain compounds

Life Science PROTAC PROTAC Linker

Chemical Biology Pharmaceutical Development and Drug Discovery Research Reagents Proteolysis Targeting Chimera Research Reagents

Biochemistry Pharmaceutical Development and Drug Discovery Research Proteolysis Targeting Chimera Research Reagents

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tert-Butyl 8-bromooctanoate

CAS No. 77383-17-6

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