(Ir[4-t-Bu-Phenyl-4-t-Bu-Py]2(dtbpy))PF6

Name: (Ir[4-t-Bu-Phenyl-4-t-Bu-Py]2(dtbpy))PF6
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

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CAS No. 808142-80-5
Cat. No. CS-0082801
Purity≥97%
MDL No.MFCD28369262

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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(Ir[4-t-Bu-Phenyl-4-t-Bu-Py]2(dtbpy))PF6|CS-0082801

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Description

This iridium(III) complex features a sterically shielded bipyridine ligand framework, enhancing solution stability and facilitating efficient phosphorescence. The bulky tert-butyl groups minimize aggregation and quenching pathways, enabling high quantum yield emission in OLED applications under standard conditions.

Application

[4,4'-Di-t-butyl-2,2'-bipyridine][bis[5-(t-butyl)-2-[4-(t-butyl)-2-pyridinyl-kN]phenyl-kC]iridium(III) hexafluorophosphate] serves as a robust, bench-stable iridium(III) complex for OLED applications. Its sterically shielded bipyridine and aryl ligands enhance thermal and oxidative stability, facilitating efficient phosphorescence in device architectures. The complex exhibits high quantum yield and good film-forming properties, enabling reliable use in solution-processed organic light-emitting diodes.

General Information

CAS No. 808142-80-5
Cat. No. CS-0082801
Purity ≥97%
MDL No. MFCD28369262
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₅₆H₇₂F₆IrN₄P
Molecular Weight 1138.38
Synonym(s) None
SMILES CC(C)(C)C1=CC2=C(C3=[N]([Ir+]245([N]6=CC=C(C(C)(C)C)C=C6C7=[N]5C=CC(C(C)(C)C)=C7)C8=CC(C(C)(C)C)=CC=C8C9=[N]4C=CC(C(C)(C)C)=C9)C=CC(C(C)(C)C)=C3)C=C1.F[P-](F)(F)(F)(F)F

Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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