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CS-W001157 4
Total: USD 88.00

Triphenylphosphine gold triflimide

  • CAS No. 866395-16-6

  • Cat. No. CS-0035276
  • Molecule weight739.40
  • Purity≥98%
  • MDL No.MFCD12911910

*For research and further manufacturing use only, not for direct human use.

Triphenylphosphine gold triflimide|CS-0035276

Structure of 866395-16-6

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General Information

  • CAS No. 866395-16-6
  • Cat. No. CS-0035276
  • Purity ≥98%
  • MDL No. MFCD12911910
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₀H₁₅AuF₆NO₄PS₂
  • Molecular Weight 739.40
  • Synonym(s) (Triphenylphosphine)Gold(I) Bis(Trifluoromethanesulfonyl)Imidate
  • SMILES O=S(N(S(=O)(C(F)(F)F)=O)[Au][P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)(C(F)(F)F)=O

Description

Triphenylphosphine gold triflimide delivers a stable, moisture-tolerant source of Au(I) for catalytic transformations. This phosphine-gold complex features a triflimide counterion that enhances solubility and reactivity in polar media. The triphenylphosphine ligand provides steric bulk and electronic stabilization, enabling efficient coordination in gold-catalyzed C–H functionalization and alkyne activation reactions under mild conditions.

Application

Triphenylphosphine gold triflimide serves as a stable, bench-friendly source of Au(I) for catalytic transformations, enabling efficient C–H activation and cyclization reactions. Its functional group tolerance and compatibility with polar solvents facilitate reliable synthesis of complex heterocycles and medicinally relevant scaffolds in standard organic workflows.

Synthesis

  • Route1
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      1176664-00-8
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    • In-stock
      Triphenylphosphine gold triflimide|CS-0035276
      866395-16-6

    References

    • Weber, Dieter; Tarselli, Michael A.; Gagne, Michel R. Angewandte Chemie, International Edition, 2009 , vol. 48, p. 5733 - 5736 Angewandte Chemie, 2009 , vol. 121, p. 5843 - 5846
  • Route2
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      1176663-98-1
    • null|null
      82113-65-3
    • ~%
    • In-stock
      Triphenylphosphine gold triflimide|CS-0035276
      866395-16-6

    References

    • Weber, Dieter; Tarselli, Michael A.; Gagne, Michel R. Angewandte Chemie, International Edition, 2009 , vol. 48, p. 5733 - 5736 Angewandte Chemie, 2009 , vol. 121, p. 5843 - 5846
  • Route3
    • null|null
      1176663-98-1
    • ~%
    • In-stock
      Triphenylphosphine gold triflimide|CS-0035276
      866395-16-6

    References

    • Weber, Dieter; Tarselli, Michael A.; Gagne, Michel R. Angewandte Chemie, International Edition, 2009 , vol. 48, p. 5733 - 5736 Angewandte Chemie, 2009 , vol. 121, p. 5843 - 5846

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05
Signal Word : Danger
UN#: 1759
Class : 8
Packing Group : Ⅲ
Hazard Statements : H314
Precautionary Statements : P260-P264-P280-P301+P330+P331-P304+P340-P363-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   71.52
  • LogP   3.6265
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   7

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