Methyl 5-bromo-4-methylpicolinate

Name: Methyl 5-bromo-4-methylpicolinate
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CAS No. 886365-06-6
Cat. No. CS-W009204
Purity≥95%
MDL No.MFCD07375102

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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Methyl 5-bromo-4-methylpicolinate|CS-W009204

Structure of 886365-06-6

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Description

Methyl 5-bromo-4-methylpicolinate is a halogenated pyridine derivative featuring a bromine atom at the 5-position and a methyl group at the 4-position, enabling selective functionalization in synthetic routes. The ester functionality enhances solubility and reactivity, facilitating coupling reactions under standard conditions. This compound serves as a key intermediate in the development of bioactive heterocycles and pharmaceutical scaffolds.

Application

Methyl 5-bromo-4-methylpicolinate serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling palladium-catalyzed cross-coupling reactions due to its well-defined bromine handle. The methyl ester functionality offers compatibility with standard hydrolysis and derivatization protocols, while the 4-methyl group provides steric and electronic modulation. Bench-stable and readily purified by column chromatography, it facilitates efficient access to substituted pyridine scaffolds common in API development.

General Information

CAS No. 886365-06-6
Cat. No. CS-W009204
Purity ≥95%
MDL No. MFCD07375102
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₈BrNO₂
Molecular Weight 230.06
Synonym(s) Methyl 5-bromo-4-methylpyridine-2-carboxylate; 5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER
SMILES O=C(C1=NC=C(Br)C(C)=C1)OC

Computational Chemistry Data

TPSA 39.19
LogP 1.93912
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 5-bromo-4-methylpicolinate

CAS No. 886365-06-6

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