Ni-(S)-BPB-GLy

Name: Ni-(S)-BPB-GLy
Brand: ChemScene
Availability: InStock
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CAS No. 96293-19-5
Cat. No. CS-M2877
Purity≥97%
MDL No.MFCD00216960

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

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Structure of 96293-19-5

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Description

Ni-(S)-BPB-GLy delivers a chiral, bench-stable ligand platform for asymmetric catalysis, featuring a rigid bicyclic scaffold that enforces stereocontrol. This nickel complex integrates a boronate ester group with a glycine-derived chiral backbone, enabling efficient cross-coupling under mild conditions. The system exhibits high enantioselectivity in C–C bond formation, particularly suited for late-stage functionalization of bioactive molecules.

Application

Ni-(S)-BPB-GLy serves as a highly effective chiral catalyst for asymmetric hydrogenation reactions, enabling enantioselective synthesis of valuable β-amino acid derivatives and pharmaceutical intermediates. Its robust bench stability and excellent functional group tolerance facilitate straightforward purification and scalability in industrial R&D workflows. The ligand’s well-defined stereochemistry ensures high enantiomeric excess in target molecules, making it a reliable choice for constructing chiral scaffolds in medicinal chemistry applications.

General Information

CAS No. 96293-19-5
Cat. No. CS-M2877
Purity ≥97%
MDL No. MFCD00216960
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₇H₂₅N₃NiO₃
Molecular Weight 498.20
Synonym(s) Ni-(S)-BPB-GLy(S)-[O-[(N-Benzylprolyl)amino](phenyl)methyleneiminoacetate(2-)-N,N',N''-nickel(II)
SMILES O=C([N-]1[Ni+2]23[N](CC([O-]2)=O)=C(C4=CC=CC=C4)C5=CC=CC=C15)[C@@]6([H])[N@]3(CC7=CC=CC=C7)CCC6

Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

Safety Information

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GHS Pictogram :	GHS No : GHS07,GHS08
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335-H351-H361
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Ni-(S)-BPB-GLy

CAS No. 96293-19-5

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