Methyl 2-bromo-6-methylbenzoate

Name: Methyl 2-bromo-6-methylbenzoate
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 99548-56-8
Cat. No. CS-W004694
Purity≥97%
MDL No.MFCD09260938

HazMat Fee +

HazMat Fee

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it. There is a HazMat shipping fee for each item that qualifies as a dangerous good, except in the following scenarios:

The shipment is processed through FedEx Ground under the Limited Quantity option.

Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

Methyl 2-bromo-6-methylbenzoate|CS-W004694

Structure of 99548-56-8

Size

Price

Quantity

* Please select Quantity before adding items.

Description

Methyl 2-bromo-6-methylbenzoate features a bromine atom at the ortho position relative to the ester, paired with a methyl group at the para position on the benzene ring. This electron-deficient aromatic system enables direct functionalization in cross-coupling reactions. The compound exhibits high stability under standard conditions and integrates readily into synthetic sequences requiring halogenated aromatics.

Application

Methyl 2-bromo-6-methylbenzoate serves as a versatile building block for transition-metal-catalyzed cross-coupling reactions, enabling efficient construction of biaryl and heteroaryl scaffolds. The ortho-bromo substituent facilitates palladium-catalyzed coupling with boronic acids, stannanes, and amines, while the methyl and ester groups offer complementary handles for further functionalization. Its bench-stable crystalline form simplifies handling and purification, making it well-suited for iterative synthesis in medicinal chemistry and materials science applications.

General Information

CAS No. 99548-56-8
Cat. No. CS-W004694
Purity ≥97%
MDL No. MFCD09260938
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₉BrO₂
Molecular Weight 229.07
Synonym(s) Methyl 6-bromo-o-toluate, 3-Bromo-2-(methoxycarbonyl)toluene
SMILES BrC1=C(C(=O)OC)C(=CC=C1)C

Computational Chemistry Data

TPSA 26.3
LogP 2.54412
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

To search for quality control of cas , please enter both the product number and the lot/batch number.

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

Methyl 2-bromo-6-methylbenzoate sigmaMethyl 2-bromo-6-methylbenzoate manufacturerMethyl 2-bromo-6-methylbenzoate priceMethyl 2-bromo-6-methylbenzoate structureMethyl 2-bromo-6-methylbenzoate SDSbuy Methyl 2-bromo-6-methylbenzoateMethyl 2-bromo-6-methylbenzoate supplierMethyl 2-bromo-6-methylbenzoate usesMethyl 2-bromo-6-methylbenzoate molecular weightprice of Methyl 2-bromo-6-methylbenzoateMethyl 2-bromo-6-methylbenzoate chemical name formula of Methyl 2-bromo-6-methylbenzoate

Salutation:	*Country or Region:
*Applicant Name:	*Organization Name:
*Email Address:	Quantity:
CAS NO. :	Product Name:
Remarks:
Upload Pictures

CAS.No.		Product Name
Applicant Name *		Email Address *
Phone Number *		Organization Name*
Country or Region*		Quantity*
Remarks:

Product Name:
Cat. No.: .		CAS NO. :
Quantity:

Methyl 2-bromo-6-methylbenzoate

CAS No. 99548-56-8

Recommended Products