3-Bromo-2-methoxyaniline

CAS No. 116557-46-1
Cat. No. CS-W006132
Purity≥98%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 116557-46-1

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Description

3-Bromo-2-methoxyaniline features a bromine substituent at the meta position relative to the amino group and a methoxy group ortho to the amine. This electron-rich aromatic scaffold enables direct coupling in cross-coupling reactions and serves as a key intermediate in the synthesis of functionalized pharmaceuticals and agrochemicals.

Application

3-Bromo-2-methoxyaniline serves as a versatile building block in medicinal chemistry, enabling direct incorporation into heterocyclic scaffolds via electrophilic substitution or cross-coupling reactions. The ortho-methoxy group enhances solubility and modulates reactivity, while the bromine facilitates palladium-catalyzed couplings. Bench-stable and readily purified, it functions effectively in standard synthetic workflows for API development and target-oriented synthesis.

General Information

CAS No. 116557-46-1
Cat. No. CS-W006132
Purity ≥98%
MDL No. None
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₈BrNO
Molecular Weight 202.05
Synonym(s) 3-Bromo-o-anisidine
SMILES NC1=CC=CC(Br)=C1OC

Computational Chemistry Data

TPSA 35.25
LogP 2.0399
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Bromo-2-methoxyaniline

CAS No. 116557-46-1

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