Methyl 6-bromo-5-fluoropicolinate

CAS No. 1210419-26-3
Cat. No. CS-0081033
Purity≥97%
MDL No.MFCD14698111

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Methyl 6-bromo-5-fluoropicolinate|CS-0081033

Structure of 1210419-26-3

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Description

Methyl 6-bromo-5-fluoropicolinate is a fluorinated heterocyclic ester featuring strategic halogen substitution at the 6-position (bromine) and 5-position (fluorine), enabling selective cross-coupling reactions. This bench-stable, moisture-tolerant building block integrates readily into complex molecular architectures via palladium-catalyzed transformations, offering enhanced reactivity and regiocontrol in synthetic workflows.

Application

Methyl 6-bromo-5-fluoropicolinate serves as a versatile building block in heterocyclic synthesis, enabling palladium-catalyzed cross-coupling reactions due to its orthogonal halogen reactivity. The bromine and fluorine substituents provide complementary functionalization handles, facilitating sequential transformations. Its bench-stable nature and ease of purification support reliable use in medicinal chemistry campaigns and API intermediate development.

General Information

CAS No. 1210419-26-3
Cat. No. CS-0081033
Purity ≥97%
MDL No. MFCD14698111
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₅BrFNO₂
Molecular Weight 234.02
Synonym(s) Methyl 6-bromo-5-fluoropyridine-2-carboxylate
SMILES COC(C1=CC=C(F)C(Br)=N1)=O

Computational Chemistry Data

TPSA 39.19
LogP 1.7698
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P264-P270-P330

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 6-bromo-5-fluoropicolinate

CAS No. 1210419-26-3

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