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CS-W001157 4
Total: USD 88.00

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

  • CAS No. 12289-94-0

  • Cat. No. CS-0035186
  • Purity≥98%
  • MDL No.MFCD00216965
  • HazMat Fee +

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    The shipment is processed through FedEx Ground under the Limited Quantity option.

    Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

    If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

    Type
    HazMat Fee
    Excepted Quantity $0.00
    FedEx Limited Quantities Ground $0.00
    Hazmat Ground shipping $50.00+
    Inaccessible (Haz class 6.1 or 9), Domestic $68.00+
    Accessible (Haz class 3, 4, 5 or 8), Domestic $158.00+
    Inaccessible (Haz class 6.1 or 9), International $108.00+
    Accessible (Haz class 3, 4, 5 or 8), International $238.00+

    An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

    There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)|CS-0035186

Structure of 12289-94-0

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Description

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is a bench-stable, air-tolerant ruthenium complex featuring two 2-methylallyl ligands and a chelating 1,5-cyclooctadiene moiety. This well-defined precatalyst integrates readily into catalytic cycles for allylic substitutions, C–H functionalizations, and cross-coupling reactions under mild conditions.

Application

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) serves as a robust precatalyst for transfer hydrogenation and olefin isomerization reactions. Its bench-stable nature and compatibility with diverse functional groups enable reliable execution of catalytic transformations under mild conditions. The ligand framework facilitates facile ligand exchange and turnover in standard synthetic workflows, making it well-suited for applications in complex molecule synthesis and process chemistry.

General Information

  • CAS No. 12289-94-0
  • Cat. No. CS-0035186
  • Purity ≥98%
  • MDL No. MFCD00216965
  • Storage -20°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₆H₂₆Ru
  • Molecular Weight 319.45
  • Synonym(s) None
  • SMILES CCC.CCC.C1/C=C\CC/C=C\C1.[Ru]

Computational Chemistry Data

  • TPSA   0
  • LogP   5.5029
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   0

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02
Signal Word : Danger
UN#: 3395
Class : 4.1
Packing Group :
Hazard Statements : H261
Precautionary Statements : P210-P240-P241-P280-P370+P378

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