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CS-W001157 4
Total: USD 88.00

Carbonylchlorobis(triphenylphosphine)iridium(I)

  • CAS No. 14871-41-1

  • Cat. No. CS-0082576
  • Purity≥98%
  • MDL No.MFCD00009590

*For research and further manufacturing use only, not for direct human use.

Carbonylchlorobis(triphenylphosphine)iridium(I)|CS-0082576

Structure of 14871-41-1

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General Information

  • CAS No. 14871-41-1
  • Cat. No. CS-0082576
  • Purity ≥98%
  • MDL No. MFCD00009590
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃₇H₃₀ClIrOP₂
  • Molecular Weight 780.27
  • Synonym(s) Vaska's Catalyst
  • SMILES Cl[Ir-]([C+]=O)[P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Description

BP Fluor 350 Picolyl Azide is a blue-fluorescent azide-activated probe that reacts with terminal alkynes via a copper-catalyzed click reaction (CuAAC). It also reacts with strained cyclooctyne via a copper-free click chemistry reaction to form a stable triazole and does not require Cu-catalyst or elevated temperatures.

Application

Carbonylchlorobis(triphenylphosphine)iridium(I) serves as a well-established precatalyst in homogeneous iridium-catalyzed transformations, particularly in hydrogenation and C–H functionalization reactions. Its bench-stable nature, tolerance to air and moisture under controlled conditions, and predictable reactivity facilitate reliable catalytic turnover. The ligand environment enables selective activation of H₂ and polar substrates, making it a practical choice for synthetic workflows requiring robust and reproducible catalysis.

Safety Information

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GHS Pictogram :
GHS No : GHS06
Signal Word : Danger
UN#: 2811
Class : 6.1
Packing Group : Ⅲ
Hazard Statements : H302-H312-H331
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P363-P405-P501

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Computational Chemistry Data

  • TPSA   17.07
  • LogP   3.467
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   5

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